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Tagged with elimination synthesis
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Mechanism of this addition-elimination process
In Part 1 of the synthesis of Maoecrystal V (found on synarchive), the last step subjects a $\ce {\alpha, \beta}$-unsaturated ketone to $\ce {I2}$ and pyridine, as shown below:
I am wondering what is ...
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What are the organic reactions that are taking place in this reaction?
I know that A is the product of a Knoevenagel condensation between the aldehyde and the diethyl malonate, due to the acidic protons of the latter, but I don't know what the reaction between that ...
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Origin of alkenes from Wurtz Reaction
According to Wikipedia:
Also, since the reaction involves free radical species, a side reaction occurs to produce an alkene. This side-reaction becomes more significant when the alkyl halides are ...
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