All Questions
Tagged with electrons physical-chemistry
98
questions
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134
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Can use lead(II) oxide instead of lead(IV) oxide in car battery?
Question: If the discharge input equation $\ce{PbO2}$ is replaced by $\ce{PbO}$, will the battery still work? I think the product will not be water anymore but hydrogen gas. I am asking this question ...
0
votes
1
answer
93
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Hydrated electrons produced by radiation vs electrons from electrostatic charge: are they equally reactive?
One of the species generated in water or aqueous solutions by the ionizing radiations are free electrons that quickly become "hydrated" or "aqueous electrons" (see for example this ...
2
votes
2
answers
444
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How to find the angle of emission of an X-ray during impact of accelerated cathode rays?
X rays are produced when accelerated cathode rays strike a metal target or a metal anode.
How can we find the angle at which the X-ray is emitted from the metal anode or the target when the cathode ...
1
vote
0
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103
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Maximum number of Spectral Lines "A better quantum model shows that there will be n^2 transitions"?
I was parsing the following post What is the maximum number of emission lines when the excited electron of a H atom in n = 6 drops to ground state? and came across with the reply from @porphyrin.
cite ...
-1
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2
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93
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Confusion regarding orbital, electron and Quantum no’s [closed]
Now , In some textbook I have read that orbital is nothing but the shape of electron . s,p,d orbitals etc.
So , after knowing shape of an orbital . I got to know that inside the orbital is an electron ...
2
votes
0
answers
75
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Number of π electrons in all trans-2,4,6-octatrienoic acid
Sketch the Lewis structure of all trans-2,4,6-octatrienoic acid.
(a) Consider the delocalized π electrons. Employ the particle-in-a-box model. Drawing on your knowledge about the occupation of ...
2
votes
1
answer
52
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In Energy-Dispersive X-ray Spectroscopy, do higher atomic elements ever generate just K lines without L or M lines?
The heavier elements only show L or M lines. Is that because the critical ionisation energy is too high to get K lines in higher atomic numbers? Can you ever get just the K lines, or just the M lines ...
-3
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1
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How to determine the number of electron in a shell [duplicate]
My textbook has been mentioned that the maximum number of electron in a shell is 2n² and the octet rule. It has also said that period number signifies the number of electron shells of an element and ...
0
votes
1
answer
784
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How does the charge imbalance affect the cell reaction when there is no salt bridge in a galvanic cell?
As mentioned in the answers to this question Why is it important to use a salt bridge in a voltaic cell? Can a wire be used? a salt bridge is used to keep the two half cells neutral. i understand how ...
1
vote
2
answers
660
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How come we can't use the equivalence point equation of NV=NV in this problem?
So, the problem is you prepare to standardize a $\ce{Na2S2O3}$ solution. $\pu{32 mL}$ of $\ce{Na2S2O3}$ solution is titrated into $\pu{50 mL}$ of a $\pu{0.01 M} \ \ce{KIO3}$ solution to reach the ...
5
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1
answer
175
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Does an orbital have its own energy, separate from the electron? Can I picture them as a entity independent from the hosted particle? [closed]
Does an orbital have its own energy, separate from the electron? If so, is it possible for an electron to have a different energy than the orbital it occupies?
0
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1
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Why oxidation potential of an electrode equals negative reduction potential of the same electrode?
My textbook states that:
$E^\circ_\mathrm{ox} = -E^\circ_\mathrm{red}$ (of same electrode)
I know that electrons flow from anode half cell (oxidation) to cathode half cell (reduction).
But if $E^\...
4
votes
0
answers
176
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Has a concept of temperature ever been defined in the context of a single atom?
I wonder if this answer to What would happen if we supercool and then superheat an atom very abruptly? goes far enough.
I almost wrote the comment:
I don't think we can even talk about the ...
2
votes
2
answers
159
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Why does an electron lose energy so that it falls back to a lower energy state than just stay at the higher energy state?
Suppose an electron in the 2nd shell gets excited and jumps to the 4th shell. Shouldn't the electron then exist in an unstable equilibrium in the 4th shell, than lose energy and drop down to the 2nd ...
1
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0
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35
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Properties that probe electron kinetic energy
This post is inspired by a question regarding the meaning of off-diagonal elements of the KE matrix (in some AO basis). One answer suggests that a diagonalized KE matrix might not be very useful. I ...