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3
votes
1
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Why is the OO-H dissociation is unlikely for the Caro's Acid?
Let us consider the Caro's Acid: $\mathrm{H_2SO_5 \equiv SO_3H-OOH}$.
It is widely known that the hydrogen tied with the $\mathrm{-OO-}$ group is pretty much unlikely to dissociate:
$$ \text {...
7
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D6h symmetry clusters- orbital classification confusion!
I was am simulating high symmetry clusters D6h in several programs such as molcas and gaussian. I understand that the highest symmetry used in these programs is D2h and therefore there would be mixing ...