All Questions
10
questions
4
votes
1
answer
234
views
How does a silver chloride electrode (Ag/AgCl) convert the potential in aqueous solution to the wire?
I am aware of the redox chemistry that happens at the electrode surface, but I'm not sure how exactly a change in electrical potential in the solution would change the potential in the electrode?
- 41
1
vote
1
answer
86
views
Incompatibility of Helmholtz Double Layer and Redox electrochemistry
In an electric double layer capacitor(EDLC) (or any situation with a Helmholtz double layer) what prevents the ions from being reduced or oxidized like the ions in an electrochemical cell?
If it is ...
2
votes
1
answer
318
views
Relation between standard silver-silver chloride electrode potential and solubility product of silver chloride
I learned that $E^\circ_\ce{Cl^-|Ag,AgCl}, E^\circ_\ce{Ag^+|Ag}$ and $K_\mathrm{sp}$ of $\ce{AgCl}$ are related as
$$\boxed{E^\circ_\ce{Cl^-|Ag,AgCl} = E^\circ_\ce{Ag^+|Ag} + \frac{RT}{F}\ln K_\mathrm{...
- 750
2
votes
1
answer
190
views
Effect of side reactions on galvanic cell using iron rod as anode and sodium chloride as salt bridge
We just made a galvanic cell on a chemistry lesson using iron, iron sulfate , copper and copper sulfate.
We used a sponge soaked in $\ce{NaCl}$ solution as the salt bridge. The issue is that we ...
2
votes
0
answers
409
views
Effect of charge density on electrolysis of dilute sulphuric acid
I am told that if electrolysis of dilute sulfuric acid is performed under high charge density, then the following reaction takes place at anode instead of evolving oxygen:
$$\ce{2 HSO4- -> H2S2O8 +...
- 363
0
votes
1
answer
165
views
How to know which reduction and oxidation reactions occurred?
We just had a lab experiment on galvanic cells and we used 0.5 M and 1 M iron(III) nitrate solution at the anode (iron electrode) and 1 M and 0.5 M copper(II) nitrate solution at the cathode (copper ...
0
votes
1
answer
146
views
Is the ionic solution of a half-cell part of the electrode in a electrochemical cell? [closed]
A simple electrochemical cell consists of two half-cells, that is: a metal solid submerged in a solution. Additionally, there is salt bridge connecting the half-cells.
Ex: $\ce{Cu(s)}$ in $\ce{CuSO4(...
3
votes
2
answers
441
views
Partial reactions in redox formation of rust
In the iron oxidation that results in rust, the first step is to steal 2 electrons from $\ce{Fe}$. The main thief is said to be the oxygen dissolved in water, witch uses the stolen electrons to form $\...
4
votes
1
answer
2k
views
Can silver metal be used to electrochemically reduce copper?
I have a solution of copper(II) ions and several cations. I am trying to reduce the copper ions to copper metal with electricity. My Ideas was to use silver as the anode and a copper wire as the ...
- 521
0
votes
1
answer
350
views
Ionize Hydrogen and Oxygen Gas in Electrolytic Cell?
As is well known, water can be electrolyzed into oxygen and hydrogen gasses. However, all redox reactions can be run in reverse. If I were to electrolyze water in 2 closed containers (in order to trap ...
- 601