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6 votes
0 answers
82 views

Do "pseudo Van der Waals" gases exist?

In college, when deriving the Langmuir isotherm for gas-solid adsorption, the professor proposed a modified version of the Van der Waals state equation, what he called the "pseudo Van der Waals ...
David Moldes's user avatar
4 votes
1 answer
255 views

Understanding isosteric enthalpy (heat) of adsorption

I am trying to understand what is isosteric heat of adsorption. Based on van't Hoff equation: $$ \left(\frac{\partial \ln K}{\partial T}\right)_θ = \frac{ΔH^\circ}{RT^2} $$ and $ΔH^\circ$ is defined ...
Anton's user avatar
  • 766
1 vote
1 answer
485 views

Finding the Freundlich adsorption isotherm from the graph of log(x/m) v/s log(p)

The following problem was asked in JEE Mains 2020 (Sept 2, Shift 1), The mass of gas adsorbed, $x$, per unit mass of adsorbate, $m$, was measured at various pressures, $p$. A graph between $\log\frac ...
Rahul Verma's user avatar
  • 3,071