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Safdar Faisal
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Minimum Ratio How to calculate the ratio of Rate Constantsrate constants of competing reactions?

There are two compounds A and B that react with one common reagent C following first order kinetics. Suppose 99.9% of A must React before 0.1% of B has reacted then what is the minimum ratio of their respective rate Constants?

There are two compounds $\ce{A}$ and $\ce{B}$ that react with one common reagent $\ce{C}$ following first order kinetics. Suppose 99.9% of $\ce{A}$ must react before 0.1% of $\ce{B}$ has reacted then what is the minimum ratio of their respective rate constants?

My Attempt at the question  :

We know that the reactions follow first order kinetics, hence I tried to find the time at which the given percentage of A$\ce{A}$ and B$\ce{B}$ is left using the formula $$ t = \frac{2.303}{k} \cdot \log\left(\frac{C_0}{C_1}\right)$$ where -$t$ is the time, $k$ is the rate constant for each reaction and $C_0$ and $C_1$ are initial and final concentration respectively.

t = 2.303/k . log(C0/C1)

where t is the time, k is the rate constant for each reaction and C0 and C1 are initial and final concentration respectively.

After this I tried to find the ratio of rate Constantsconstants directly but couldn't arrive at the answer.

P.S.

I I derived the above formula using the integrated rate law.

Minimum Ratio of Rate Constants

There are two compounds A and B that react with one common reagent C following first order kinetics. Suppose 99.9% of A must React before 0.1% of B has reacted then what is the minimum ratio of their respective rate Constants?

My Attempt at the question  :

We know that the reactions follow first order kinetics, hence I tried to find the time at which the given percentage of A and B is left using the formula -

t = 2.303/k . log(C0/C1)

where t is the time, k is the rate constant for each reaction and C0 and C1 are initial and final concentration respectively.

After this I tried to find the ratio of rate Constants directly but couldn't arrive at the answer.

P.S.

I derived the above formula using the integrated rate law.

How to calculate the ratio of rate constants of competing reactions?

There are two compounds $\ce{A}$ and $\ce{B}$ that react with one common reagent $\ce{C}$ following first order kinetics. Suppose 99.9% of $\ce{A}$ must react before 0.1% of $\ce{B}$ has reacted then what is the minimum ratio of their respective rate constants?

My Attempt at the question:

We know that the reactions follow first order kinetics, hence I tried to find the time at which the given percentage of $\ce{A}$ and $\ce{B}$ is left using the formula $$ t = \frac{2.303}{k} \cdot \log\left(\frac{C_0}{C_1}\right)$$ where $t$ is the time, $k$ is the rate constant for each reaction and $C_0$ and $C_1$ are initial and final concentration respectively.

After this I tried to find the ratio of rate constants directly but couldn't arrive at the answer. I derived the above formula using the integrated rate law.

Source Link

Minimum Ratio of Rate Constants

There are two compounds A and B that react with one common reagent C following first order kinetics. Suppose 99.9% of A must React before 0.1% of B has reacted then what is the minimum ratio of their respective rate Constants?

My Attempt at the question :

We know that the reactions follow first order kinetics, hence I tried to find the time at which the given percentage of A and B is left using the formula -

t = 2.303/k . log(C0/C1)

where t is the time, k is the rate constant for each reaction and C0 and C1 are initial and final concentration respectively.

After this I tried to find the ratio of rate Constants directly but couldn't arrive at the answer.

P.S.

I derived the above formula using the integrated rate law.