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$\begingroup$ I completely agree with the discussion about ion pairing and the decreased mobility. We study charge transport, and similar curves exist - at high concentration, the mobile charges become "frustrated" because of electrostatic interactions. $\endgroup$
– Geoff Hutchison
Commented Mar 11, 2015 at 16:57
$\begingroup$ I also wonder whether, particularly with sulfuric, if there's a density/viscosity effect at work at high concentrations. $\endgroup$
– Geoff Hutchison
Commented Mar 11, 2015 at 16:59
$\begingroup$ @GeoffHutchison viscosity effect is mentioned in this document: nist.gov/data/nsrds/NSRDS-NBS331.pdf I'll try to add more to my answer from there. $\endgroup$
– DavePhD
Commented Mar 11, 2015 at 17:30

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