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    $\begingroup$ The EQUILIBRIUM vapor pressure depends on the chemical potential of the liquid. A pure liquid with less exposure will establish the same VP but take longer to attain it. There is an effect for very small droplet size[nanodrops] where the VP is actually higher than for larger drops or bulk material. $\endgroup$
    – jimchmst
    Commented Apr 23 at 20:33
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    $\begingroup$ If the liquids are being stirred continuously... then you could just as well have them in two smaller containers and there would be no difference. $\endgroup$
    – Mithoron
    Commented Apr 24 at 0:44
  • $\begingroup$ Before asking, you may find useful reviewing the targetted search results like site:stackexchange.com OR site:libretexts.org OR site:wikipedia.org vapor pressure immiscible liquids $\endgroup$
    – Poutnik
    Commented Apr 24 at 9:12
  • $\begingroup$ @Mithoron I did check out that thread but unfortunately, it didn't answer my question. But your explanation did. Thanks! :D $\endgroup$
    – hi hi
    Commented Apr 24 at 14:18
  • $\begingroup$ @Poutnik Thanks for the suggestion. I will keep it in mind when I ask my next question. :D (sorry it's my first time asking a question here) $\endgroup$
    – hi hi
    Commented Apr 24 at 14:19