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  • $\begingroup$ So the argument of ionization energy is invalid. It all makes sense now. $\endgroup$ Commented Oct 21, 2022 at 0:20
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    $\begingroup$ I think so. There is Saha equation that talks about ionization but that is for stars but some people did connect to flame spectroscopy as well. I studied this decades ago. $\endgroup$
    – ACR
    Commented Oct 21, 2022 at 0:27