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First save your print settings as a preset:

• Open a document, then choose File > Print. Click Show Details.
• Choose any print settings you want to save as a preset.
• Click the Presets pop-up menu, then choose Save Current Settings as Preset.
• Enter a name for the preset settings, then choose whether to use the preset for only the currently selected printer or all printers.

Then make that preset as default: hold the Option (alt) key when choosing your preset, and it will become Default.

First save your print settings as a preset:

• Open a document, then choose File > Print. Click Show Details.
• Choose any print settings you want to save as a preset.
• Click the Presets pop-up menu, then choose Save Current Settings as Preset.
• Enter a name for the preset settings, then choose whether to use the preset for only the currently selected printer or all printers.

Then make that preset as default: hold the Option (alt) key when choosing your preset, and it will become Default.

Source: https://web.archive.org/web/20131005034126/http://support.apple.com/kb/PH10768

First save your print settings as a preset:

• Open a document, then choose File > Print. Click Show Details.
• Choose any print settings you want to save as a preset.
• Click the Presets pop-up menu, then choose Save Current Settings as Preset.
• Enter a name for the preset settings, then choose whether to use the preset for only the currently selected printer or all printers.

Then make that preset as default: hold the Option (alt) key when choosing your preset, and it will become Default.

Source https://support.apple.com/kb/PH10768

First save your print settings as a preset:

• Open a document, then choose File > Print. Click Show Details.
• Choose any print settings you want to save as a preset.
• Click the Presets pop-up menu, then choose Save Current Settings as Preset.
• Enter a name for the preset settings, then choose whether to use the preset for only the currently selected printer or all printers.

Then make that preset as default: hold the Option (alt) key when choosing your preset, and it will become Default.

Apple has a support document describing the steps required to do so.

First save your print settings as a preset:

• Open a document, then choose File > Print. Click Show Details.
• Choose any print settings you want to save as a preset.
• Click the Presets pop-up menu, then choose Save Current Settings as Preset.
• Enter a name for the preset settings, then choose whether to use the preset for only the currently selected printer or all printers.

Then make that preset as default: hold the Option (alt) key when choosing your preset, and it will become Default.

First save your print settings as a preset:

• Open a document, then choose File > Print. Click Show Details.
• Choose any print settings you want to save as a preset.
• Click the Presets pop-up menu, then choose Save Current Settings as Preset.
• Enter a name for the preset settings, then choose whether to use the preset for only the currently selected printer or all printers.

Then make that preset as default: hold the Option (alt) key when choosing your preset, and it will become Default.

Source https://support.apple.com/kb/PH10768