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  • "C:\Users\Username\Documents\WindowsPowerShell\Modules" - This would only exist in the user's PATH variable. It appears you are modifying the user's PATH variable instead of the system's PATH variable hence the difference. This question has an answer that explains the differences.
    – Ramhound
    Commented Jul 16, 2018 at 19:55
  • 1
    @PimpJuiceIT, just open System Properties\Advanced\Environment Variables and take a look in there yourself. If you use the actual UI, or even check the corresponding registry entry, you can see the percentage signs in the text string. The problem is that I cannot get the string with the percentage signs using PowerShell for some reason; they always get converted to hard-coded paths and I don't know why.
    – EllipticalInitial
    Commented Jul 17, 2018 at 17:06