In your own post you show the size of tethe file to be 4.76GB. That is over the maximum filesize for FAT.
You have these options:
- Reformat with another (more modern) filesystem which supports files over 4GiB.
- Split the file in part smaller than 4GiB.
- Create multiple files (each less than 4GiB) on the pendrive and loopback mount those in stripe.
(The last is technicalllytechnically possible, but unless you like a challenge I would skip it).