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Unanswered Questions

203 questions with no upvoted or accepted answers
7 votes
0 answers
1k views

Why isn't orthoboric acid soluble in cold water even though it has polar B-OH bonds?

This is the information I found regarding orthoboric acid's solubility: Textbook (NCERT India): Sparingly soluble in water (didn't say what temperature - presumably cold) and highly soluble in hot ...
7 votes
0 answers
204 views

What factors contribute most to solubility of ionic substances in highly polar solvents, esp. ionic liquids and DES?

I am trying to determine a method to dissolve a mineral salt with a lattice energy of ≈18000 kJ/mol. I know that lattice energy is the most significant factor affecting solubility of an ionic ...
6 votes
0 answers
2k views

Yellow precipitate in SnCl2 solution

I have a few small bottles of 0.5M $\ce{SnCl2}$ solution, however solution was prepared about 4 months ago, and there is a yellow precipitate on the bottom of each bottle. Working hypothesis is that ...
6 votes
0 answers
187 views

Alkali Metal Rosinates Solubility in Acetone

In violin finishing technology alkali metal Rosinates are used in varnish synthesis. Usually this alkali metal Rosinates are soluble in Turpentine. I also know that Copper, Zinc Rosinates are soluble ...
5 votes
0 answers
357 views

Solubility of pyridine and pyrrole in water

Pyridine and pyrrole are two of the first aromatic heterocycles encountered in organic chemistry. Recently, I was surprised to find that their solubility properties are vastly different. The website ...
5 votes
0 answers
170 views

Does chromium(III) oxide react with or dissolve in liquid sulfur dioxide?

Liquid $\ce{SO2}$ (b.p. −10 °C) is known as a versatile solvent (yet not particularly pleasant to work with) for a wide range of organic and inorganic compounds having limited solubility in ...
5 votes
0 answers
352 views

Why does beryllium have an exceptionally high hydration energy?

You would expect solubility of Group $2$ fluorides to increase down the group, as lattice energy plummets much more sharply than hydration energy does. For the most part, this is true: $\ce{BaF2}$ is ...
5 votes
0 answers
161 views

Does π values vary in Hansch-Fujita equations for a given substituent?

I was reading about Hansch-Fujita equations from Hansch-Fujita paramaters and observed that the $π$ values of substituents (analogous to Hammet $σ$ values) change according to the specific environment ...
5 votes
0 answers
237 views

What acids, solvents is lithium-6 fluoride soluble in (other than HF)?

$\ce{LiF}$ is quite insoluble in water, and I'm trying to use some water-soluble acid or solvent to dissolve $\ce{^6LiF}$ (95% enriched) in. I'm not a chemistry person, I'm a radiation detection ...
5 votes
0 answers
793 views

Solubility of PbSO4

The solubility of $\ce{PbSO4(s)}$ increase with the addition of $\ce{H2SO4}.$ Why? I don't quite understand this. When dissolving $\ce{PbSO4(s)}$ we get the equilibrium equation: $$\ce{PbSO4(s) <=...
5 votes
0 answers
115 views

UV curable adhesive

I'm looking for a UV curable adhesive that can be removed without peeling or burning. Ideal removal would be some kind of solvent over a relatively short period of time. I also need it to have a ...
4 votes
0 answers
101 views

Dominant factors rendering very low solubility of large aromatic molecules

In terms of structural basis, alkanes are insoluble or immiscible in water because of such presence of C–H...O interactions that are in regime of van der Waals interaction, which tends to be regarded ...
4 votes
0 answers
119 views

How to use Sodium Thiosulfate for fixing dicopper (I) tetraiodomercurate (II)?

DISCLAIMER DO NOT TRY TO DEMERCURATE USING DESCRIBED PROCEDURE. CONSULT YOUR EMERGENCY SERVICE. I found a discrepancy between a government-approved procedure of living quarters demercuration and the ...
4 votes
0 answers
2k views

Why is potassium bitartrate so insoluble?

The solubility of potassium bitartrate in water at 20°C is given by Wikipedia as 0.57 g per 100 ml, which is considerably lower than that of sodium bitartrate. Generally, a potassium salt is more ...
4 votes
0 answers
690 views

Theory of volume contraction in solution

When a solid is dissolved into a liquid, or two solids are amalgamated, their mutual volume will contract. For example, a crystal of sugar having a volume of one cubic inch dissolved into 10 cubic ...

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